[N-(2-Hydroxyethyl)ethylenediamine]-oxalatocopper(II)-oxalatocopper(II)


Paşaoǧlu H., Kaştşa G., YEŞİLEL O. Z., YILDIRIM M.

Acta Crystallographica Section E: Structure Reports Online, cilt.65, sa.11, 2009 (SCI-Expanded, Scopus) identifier identifier

Özet

In the title mononuclear copper(II) compound, [Cu(C2O 4)(C4H12N2O)], the CuII ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy-ethyl)ethyl-enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex mol-ecules participate in a supra-molecular assembly through N- H⋯O and O- H⋯O hydrogen bonds between HydEt-en and ox ligands.