Molecular Structure and Supramolecular Architecture of (E)-2-Bromo-6-[(2,4,6-Tribromophenylimino)methyl]-4-Chlorophenol

Albayrak Kaştaş Ç., KAŞTAŞ G., Kırca B. K., Ersanlı C.

Crystallography Reports, cilt.65, sa.7, ss.1106-1110, 2020 (SCI-Expanded, Scopus) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 65 Sayı: 7
  • Basım Tarihi: 2020
  • Doi Numarası: 10.1134/s1063774520070093
  • Dergi Adı: Crystallography Reports
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chemical Abstracts Core, Compendex, INSPEC, zbMATH
  • Sayfa Sayıları: ss.1106-1110
  • Samsun Üniversitesi Adresli: Evet

Özet

Abstract: In this study, the molecular structure and supramolecular architecture of a new compound have been studied in depth using single crystal X-ray diffraction (XRD) technique. Crystallographic results show that the compound exists in phenol-imine form that is twisted with the dihedral angle of 51.77° between the aromatic rings of the molecule. Various types of non-covalent interactions (C⋅⋅⋅O, C–H⋅⋅⋅O, Br⋅⋅⋅Br, C–H⋅⋅⋅Cl, π⋅⋅⋅π, O⋅⋅⋅Br, and Br⋅⋅⋅π) take part effectively in the construction of 3D network in the compound. The C⋅⋅⋅O and C–H⋅⋅⋅O interactions have the role of forming the 1D structure along the direction [010] with the support of π⋅⋅⋅π and π⋅⋅⋅Br interactions. The 2D structure of the compound is reached by the inter-connection of 1D chains in the (101) plane through the C–H⋅⋅⋅Cl interactions. The 3D supramolecular structure of the compound is completed by the non-covalent Br⋅⋅⋅Br and Br⋅⋅⋅O interactions responsible for the connection of 2D sheets.