Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine-κ5 O,N,N′,O′,O′′]nickel(II) tetrahydrate

KANSIZ, SEVGİ; Dege, Necmi; Topcu, Yıldıray; Atalay, Yusuf; Gaidai, Snizhana

doi:10.1107/s2056989018015359

Crystal structure and Hirshfeld surface analysis of (succinato-κO)[N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine-κ5 O,N,N′,O′,O′′]nickel(II) tetrahydrate

KANSIZ S., Dege N., Topcu Y., Atalay Y., Gaidai S. V.

Acta Crystallographica Section E: Crystallographic Communications, cilt.74, ss.1700-1704, 2018 (Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 74
Basım Tarihi: 2018
Doi Numarası: 10.1107/s2056989018015359
Dergi Adı: Acta Crystallographica Section E: Crystallographic Communications
Derginin Tarandığı İndeksler: Scopus
Sayfa Sayıları: ss.1700-1704
Anahtar Kelimeler: crystal structure, Hirshfeld surface, nickel(II) complex, succinic acid
Samsun Üniversitesi Adresli: Hayır

Özet

In the title compound, [Ni(C10H24N2O4)(C4H4O4)]·4H2O, the NiII cation is octahedrally coordinated by one O atom of the succinate anion and three O atoms and two N atoms from an N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine molecule. In the crystal, molecules are linked by O - H⋯O and C - H⋯O hydrogen bonds, forming a three-dimensional supramolecular architecture. Hirshfeld surface analyses and two-dimensional fingerprint plots were used to analyse the intermolecular interactions present in the crystal, indicating that the most important contributions for the crystal packing are from H⋯H (63.3%) and H⋯O/O⋯H (34.5%) interactions.